劉國生

劉國生

中國科學院上海有機化學研究所研究員
劉國生,男,研究生,現為中國科學院上海有機化學研究所研究員。主要研究方向是,本課題組的研究集中在有機化學,金屬催化和材料化學的前沿交叉區域,主要基于C-M鍵的基元反應,通過設計和合成一些新型的金屬催化劑來實現有機分子的高選擇性轉化,并對反應機理的進行研究,從而能夠更多的了解這些金屬催化的反應,對金屬的基元反應更多的認識。[1]
  • 中文名:劉國生
  • 民族:
  • 出生地:
  • 畢業院校:
  • 學位/學曆:研究生
  • 職業:科研工作者
  • 專業方向:
  • 職務:中國科學院上海有機化學研究所研究員
  • 學術代表作:
  • 主要成就:

人物經曆

1991,9-1995,7南京理工大學化工學院,獲工學學士;

1996,9-1999,8中科院大連化學物理研究所,獲理學碩士;

1999,9-2002,8中科院上海有機化學研究所,獲理學博士;

2003,3-2005,7美國Lehigh大學,博士後;

2005,8-2007,7美國威斯康辛大學麥迪遜分校化學系,研究助理;

2007,7-中科院上海有機所研究員。

主要成就

科研成就

代表論著:

Wu, Liang; Qiu, Shuifa; Liu, Guosheng,* “Br?nsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.” Org. Lett. 2009, 11, 2707.

Qiu, Shuifa; Wei, Yunyang; Liu, Guosheng;* “Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.” Chem. Eur. J. 2009, 15, 2751.

Liu, Guosheng;* Yin, Guoyin; Wu, Liang; “Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: effic- ient synthesis of linear allylamine derivatives.” Angew. Chem. Int. Ed. 2008, 47, 4733.

Yin, Guoyin; Liu, Guosheng;* “Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.” Angew. Chem. Int. Ed. 2008, 47, 5442.

Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li;* Macromolecules 2008, 41, 8980.

Liu, Guosheng; Stahl, Shannon. S;* “Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.” J. Am. Chem. Soc. 2007, 129, 6328-6335.

Liu, Guosheng; Stahl, Shannon. S;* “Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN2 C-O Bond Formation”, J. Am. Chem. Soc. 2006, 128, 7179-7181.

Liu, Guosheng; Jia, Li;* “Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran”, Angw. Chem. Int. Ed. 2006, 45, 129.

Liu, Guosheng; Jia, Li;* “Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s”, J. Am. Chem. Soc. 2004, 126, 14716.

Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling of Allenoic Acids and a,b-Unsaturated Carbonyl Compounds through Tandem Intramolecular oxypalladation and Conjugate Addition Reactions”, Tetrahedron Lett. 2003, 44, 127.

Lei, Aiwen; Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino- L-xylitol”, J. Org. Chem. 2002, 67, 974.

Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalladation of Alkyne with Allylic Compounds”, Tetrahedron Lett. 2002, 43, 6791.

Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Tandem Reaction of Intramolecular Aminopalladation of Allenyl N-Tosylcarbamates and Conjugate Addition”, Org. Lett. 2001, 3, 3879.

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